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課程名稱 |
高等化工熱力學
Advanced Chemical Engineering Thermodynamics |
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開課學期 |
100-2 |
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授課對象 |
化學工程學研究所 |
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授課教師 |
諶玉真 |
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課號 |
ChemE7003 |
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課程識別碼 |
524 M1110 |
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班次 |
01 |
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學分 |
3 |
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全/半年 |
半年 |
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必/選修 |
必修 |
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上課時間 |
星期二3,4(10:20~12:10)星期四3(10:20~11:10) |
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上課地點 |
共307共307 |
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備註 |
核心課程。
限碩士班以上
總人數上限：42人 |
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Ceiba 課程網頁 |
http://ceiba.ntu.edu.tw/1002CP |
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課程簡介影片 |
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核心能力關聯 |
核心能力與課程規劃關聯圖 |
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課程大綱
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為確保您我的權利,請尊重智慧財產權及不得非法影印
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課程概述 |
This class is an extension of undergraduate chemical engineering thermodynamics course. This class discusses more extensive topics including thermodynamic properties of fluid mixtures, phase equilibrium calculations of fluid mixtures, and statistical thermodynamics. |
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課程目標 |
1. 熱力學相平衡基本原理
2. 狀態方程式應用於相平衡計算的原理
3. 汽相混合物逸壓計算方法
4. 液相混合物逸壓計算方法
5. 液相模式的理論及應用
6. 汽液相平衡、液液相平衡、氣體及固體溶解度的計算
7. 統計熱力學的原理及應用 |
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課程要求 |
Textbook Molecular Thermodynamics of Fluid-Phase Equilibria, 3rd ed., J. M. Prausnitz, R. N. Lichtenthaler, E. G. de Azevedo, Prentice Hall, New York, 1999.
Course Outline Instruction Hours remark
Topics Contents lecture demonstration experiment others1
The basic principles of thermo-
dynamics and phase equilibrium 1. Importance of phase equilibrium calculations
2. The basic method for phase equilibrium calculations
3. The Gibbs-Duhem
equation
4. Phase rule
5. Definitions of fugacity and activity 5 1
Developments of equations of states for phase equilibrium calculations
1. Virial type equations of state
2. Cubic type equations of state
3. Complex equations of state
4. Intermolecular forces
5. Corresponding states theory and generalized correlation 5 1
Calculations of fugacities for gas mixtures
1. Calculations of gas phase fugacity from equations of state
2. Associations in the gas phase
3. Solubilities of solids in supercritical fluids 5 1
Calculations of fugacities for liquid mixtures
1. Excess functions and activity coefficients
2. Thermodynamic consistency test
3. Regression of excess function parameters 5 1
Developments and applications of activity coefficient models
1. The local composition models
2. The regular solution model, Wilson, NRTL, UNIQUAC equations
3. Group contribution models and the UNIFAC equation 5 1
Vapor-liquid equilibrium, liquid-liquid equilibrium, gas solubility and solid solubility calculations
1. Vapor-liquid equilibrium calculations
2. Liquid-liquid equilibrium calculations
3. Gas solubilities in liquids
4. Solid solubilities in liquids 5 1
Principles and applications of statistical thermo-
dynamics
1. Statistics and basic postulates
2. Microcanonical ensemble
3. Canonical ensemble
4. Grand canonical ensemble
5. Quantum mechanics and physical properties of fluids
6. Generalized van der Waals partition function and its applications 8 1
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預期每週課後學習時數 |
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Office Hours |
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指定閱讀 |
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參考書目 |
Course Website or Other remarks:
http:// www.che.ntu.edu.tw/lab/therm/index.htm
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評量方式
(僅供參考) |
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